In SharePoint 2007 list, if we want to prevent duplicate values in a column, we can make use of the SPServices MakeUnque function.
More details are here:
http://spservices.codeplex.com/wikipage?title=$%28%29.SPServices.SPRequireUnique&referringTitle=Documentation
Currently, the function works only with Single line of textcolumns.
More details are here:
http://spservices.codeplex.com/wikipage?title=$%28%29.SPServices.SPRequireUnique&referringTitle=Documentation
Currently, the function works only with Single line of textcolumns.